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8-Hydroxyquinoline Benzoates as Highly Sensitive Fluorescent Chemosensors for Transition Metal Ions

Han ZhangDepartment of Chemistry and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China, and Max-Planck-Institute for Biophysical Chemistry, 37070 Göttingen, GermanyLifeng HanDepartment of Chemistry and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China, and Max-Planck-Institute for Biophysical Chemistry, 37070 Göttingen, GermanyKlaas A. ZachariasseDepartment of Chemistry and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China, and Max-Planck-Institute for Biophysical Chemistry, 37070 Göttingen, GermanyYun‐Bao JiangDepartment of Chemistry and the MOE Key Laboratory of Analytical Sciences, Xiamen University, Xiamen 361005, China, and Max-Planck-Institute for Biophysical Chemistry, 37070 Göttingen, Germany
2005en
ABI

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[graph: see text] 8-Hydroxyquinoline benzoates were developed as a new set of 8-HQ derivatives for highly sensitive fluorescent chemosensors for transition metal ions. A prominent fluorescence enhancement was found in the presence of transition metal ions such as Hg2+ and Cu2+, and this was suggested to result from the suppression of radiationless transitions from the npi state in the chemosensors.

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