Asosiy kontentga oʻtish
AkademIndex

Mahsulotlar

Ishlab chiquvchilar uchun

AkademBaseEkotizim uchun ochiq API
Maqola

Energy-level and line-strength analysis of optical transitions between Stark levels in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant="normal">Nd</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>:<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Y</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Al</mml:mi></mml:mrow><mml:mrow><mml:mn>5</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mrow><mml:mn>12</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>

Gary W. BurdickDepartment of Chemistry, University of Virginia, Charlottesville, Virginia 22901C.K. JayasankarDepartment of Chemistry, University of Virginia, Charlottesville, Virginia 22901F. S. RichardsonDepartment of Chemistry, University of Virginia, Charlottesville, Virginia 22901Michael F. ReidDepartment of Chemistry, University of Virginia, Charlottesville, Virginia 22901
1994lv
ABI

Annotatsiya

Results obtained from optical absorption measurements on ${\mathrm{Nd}}^{3+}$:${\mathrm{Y}}_{3}$${\mathrm{Al}}_{5}$${\mathrm{O}}_{12}$ (Nd:YAG) at 10 and 29 K are reported and analyzed. The low-temperature (10 K) absorption spectrum shows transitions from the lowest Stark component of the $^{4}$${\mathit{I}}_{9/2}$ (ground) multiplet to 133 of the 155 crystal-field (Stark) levels predicted to be located between 3900 and 40 000 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$, spanning 35 excited multiplet manifolds of ${\mathrm{Nd}}^{3+}$(4${\mathit{f}}^{3}$). Among the 133 transitions observed in the 10-K absorption spectrum, 97 are sufficiently well resolved to permit quantitative determination of transition line strengths. Energy levels for the $^{4}$${\mathit{I}}_{9/2}$ and $^{4}$${\mathit{I}}_{11/2}$ multiplets are taken from previously obtained optical emission measurements, and the resulting 144-level data set is analyzed in terms of a model Hamiltonian that assumes ${\mathrm{D}}_{2}$ site symmetry for the ${\mathrm{Nd}}^{3+}$ ions in Nd:YAG. Inclusion of two-electron correlation crystal-field (CCF) interaction terms in the model Hamiltonian explains the crystal-field splittings of several anomalous multiplets, and reduces the rms deviation between calculated and observed energies (for 144 levels) from 28 to 14 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$. The optical line-strength data obtained in this study are analyzed in terms of an f-f transition intensity model developed by us in previous work. This model has broad applicability in analyses of f-f intensity data for transitions between Stark levels. Emission branching ratios for transitions from the $^{4}$${\mathit{F}}_{3/2}$ multiplet are calculated and compared with literature values.

Hali tarjima qilinmagan

Identifikatorlar

Iqtiboslar va manbalar

2 ta iqtibos0 ta foydalanilgan manba