Synthesis, Structure, and Optical Properties of a Contorted <110>‐Oriented Layered Hybrid Perovskite: C<sub>3</sub>H<sub>11</sub>SN<sub>3</sub>PbBr<sub>4</sub>
Yinyan LiGraduate School of the Chinese Academy of Sciences, Beijing 100049 ChinaGuoli ZhengGraduate School of the Chinese Academy of Sciences, Beijing 100049 ChinaJun LinState Key Laboratory of Application of Rare Earth Resources, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
2008en
ABI
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Abstract The <110>‐oriented perovskite is very rare in the hybrid perovskites family. In this work, an unusual layered <110>‐oriented hybrid perovskite, which is stabilized by a special organic ligand, 2‐(aminoethyl)isothiourea, has been obtained. This ligand combines a primary amine and a formamidine on the two ends of one molecule. Introduction of the special ligand brings about contorted inorganic sheets in the hybrid perovskite structure. The optical properties of the new <110>‐oriented perovskite were studied.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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