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Hydrogen-like Wannier–Mott Excitons in Single Crystal of Methylammonium Lead Bromide Perovskite

Jenya TilchinSchulich Faculty of Chemistry, Russell Berrie Nanotechnology Institute, Solid State Institute, Technion, Haifa 32000, IsraelDmitry N. DirinDepartment of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, Zurich CH-8093, SwitzerlandGeorgy I. MaikovSchulich Faculty of Chemistry, Russell Berrie Nanotechnology Institute, Solid State Institute, Technion, Haifa 32000, IsraelAldona SashchiukSchulich Faculty of Chemistry, Russell Berrie Nanotechnology Institute, Solid State Institute, Technion, Haifa 32000, IsraelMaksym V. KovalenkoDepartment of Chemistry and Applied Biosciences, ETH Zürich, Vladimir-Prelog-Weg 1, Zurich CH-8093, SwitzerlandEfrat LifshitzSchulich Faculty of Chemistry, Russell Berrie Nanotechnology Institute, Solid State Institute, Technion, Haifa 32000, Israel

2016en

ABI

Annotatsiya

A thorough investigation of exciton properties in bulk CH3NH3PbBr3 perovskite single crystals was carried out by recording the reflectance, steady-state and transient photoluminescence spectra of submicron volumes across the crystal. The study included an examination of the spectra profiles at various temperatures and laser excitation fluencies. The results resolved the first and second hydrogen-like Wannier-Mott exciton transitions at low temperatures, from which the ground-state exciton's binding energy of 15.33 meV and Bohr radius of ∼4.38 nm were derived. Furthermore, the photoluminescence temperature dependence suggested dominance of delayed exciton emission at elevated temperatures, originating from detrapping of carriers from shallow traps or/and from retrapping of electron-hole pairs into exciton states. The study revealed knowledge about several currently controversial issues that have an impact on functionality of perovskite materials in optoelectronic devices.

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DOI: 10.1021/acsnano.6b02734

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