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Theoretical Insights on the Interaction of Uranium with Amidoxime and Carboxyl Groups

Cong‐Zhi WangGroup of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, ChinaJian‐Hui LanGroup of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, ChinaQun‐Yan WuInstitute of High Energy PhysicsQiong LuoMOE Key Laboratory of Theoretical Environmental Chemistry, Center for Computational Quantum Chemistry, South China Normal University, Guangzhou 510631, ChinaYu-Liang ZhaoGroup of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, ChinaXiang-Ke WangKey Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, ChinaZhifang ChaiGroup of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, ChinaWei‐Qun ShiGroup of Nuclear Energy Chemistry, Key Laboratory of Nuclear Radiation and Nuclear Energy Technology and Key Laboratory for Biomedical Effects of Nanomaterials and Nanosafety, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China

2014en

ABI

Annotatsiya

Recovery of uranium from seawater is extremely challenging but important for the persistent development of nuclear energy, and thus exploring the coordination structures and bonding nature of uranyl complexes becomes essential for designing highly efficient uranium adsorbents. In this work, the interactions of uranium and a series of adsorbents with various well-known functional groups including amidoximate (AO(-)), carboxyl (Ac(-)), glutarimidedioximate (HA(-)), and bifunctional AO(-)/Ac(-), HA(-)/Ac(-) on different alkyl chains (R'═CH3, R″═C13H26) were systematically studied by quantum chemical calculations. For all the uranyl complexes, the monodentate and η(2) coordination are the main binding modes for the AO(-) groups, while Ac(-) groups act as monodentate and bidentate ligands. Amidoximes can also form cyclic imide dioximes (H2A), which coordinate to UO2(2+) as tridentate ligands. Kinetic analysis of the model displacement reaction confirms the rate-determining step in the extraction process, that is, the complexing of uranyl by amidoxime group coupled with the dissociation of the carbonate group from the uranyl tricarbonate complex [UO2(CO3)3](4-). Complexing species with AO(-) groups show higher binding energies than the analogues with Ac(-) groups. However, the obtained uranyl complexes with Ac(-) seem to be more favorable according to reactions with [UO2(CO3)3](4-) as reactant, which may be due to the higher stability of HAO compared to HAc. This is also the reason that species with mixed functional group AO(-)/Ac(-) are more stable than those with monoligand. Thus, as reported in the literature, the adsorbability of uranium can be improved by the synergistic effects of amidoxime and carboxyl groups.

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DOI: 10.1021/ic500202g

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