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Synthesis of Colloidal Upconverting NaYF<sub>4</sub> Nanocrystals Doped with Er<sup>3+</sup>, Yb<sup>3+</sup> and Tm<sup>3+</sup>, Yb<sup>3+</sup> via Thermal Decomposition of Lanthanide Trifluoroacetate Precursors

John‐Christopher BoyerDepartment of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montreal, QC H4B 1R6, Canada, and Institut National de la Recherche ScientifiqueÉnergie, Matériaux et Télécommunications, Université du Québec, Varennes, QC J3X 1S2, CanadaFiorenzo VetroneDepartment of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montreal, QC H4B 1R6, Canada, and Institut National de la Recherche ScientifiqueÉnergie, Matériaux et Télécommunications, Université du Québec, Varennes, QC J3X 1S2, CanadaLouis A. CucciaDepartment of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montreal, QC H4B 1R6, Canada, and Institut National de la Recherche ScientifiqueÉnergie, Matériaux et Télécommunications, Université du Québec, Varennes, QC J3X 1S2, CanadaJohn A. CapobiancoDepartment of Chemistry and Biochemistry, Concordia University, 7141 Sherbrooke Street West, Montreal, QC H4B 1R6, Canada, and Institut National de la Recherche ScientifiqueÉnergie, Matériaux et Télécommunications, Université du Québec, Varennes, QC J3X 1S2, Canada
2006en
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Upconverting lanthanide-doped nanocrystals were synthesized via the thermal decomposition of trifluoroacetate precursors in a mixture of oleic acid and octadecene. This method provides highly luminescent nanoparticles through a simple one-pot technique with only one preparatory step. The Er3+, Yb3+ and Tm3+, Yb3+ doped cubic NaYF4 nanocrystals are colloidally stable in nonpolar organic solvents and exhibit green/red and blue upconversion luminescence, respectively, under 977 nm laser excitation with low power densities.

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