Bis(triethanolamine-<i>N</i>,<i>O</i>,<i>O</i>′)nickel(II) bis(saccharinate)
Yıldıray TopçuDepartment of Chemistry, Faculty of Arts and Science, Ondokuz Mayis University, 55139 Kurupelit Samsun, TurkeyÖ. AndaçDepartment of Chemistry, Faculty of Arts and Science, Ondokuz Mayis University, 55139 Kurupelit Samsun, TurkeyVeysel T. YılmazDepartment of Chemistry, Faculty of Arts and Science, Ondokuz Mayis University, 55139 Kurupelit Samsun, TurkeyWilliam T. A. HarrisonDepartment of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland, UK
2001he
ABI
Annotatsiya
The structure of the title compound, [Ni(C6H15NO3)2](C7H4NO3S)2, consists of a cationic [Ni(TEA)2]2+ and two anionic (SAC)− moieties (TEA is triethanolamine and SAC is the saccharinate anion). Two TEA ligands coordinate to the NiII ion through four O atoms and two N atoms acting as tridentate ligands (N,O,O′) in a distorted octahedral environment, with the bond distances [d(Ni—O) = 2.078 (2) and 2.082 (2) Å, and d(Ni—N) = 2.108 (2) Å]. SAC anions participate in intermolecular hydrogen bonding with the hydroxyl H atoms of the TEA ligands to form a three-dimensional network.
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