Negative magnetocaloric effect at the antiferromagnetic to ferromagnetic transition of Mn3GaC

The magnetocaloric effect of Mn3GaC, which shows an antiferromagnetic to ferromagnetic transition at 165 K has been investigated. In this compound, magnetocaloric effect obtained at the transition is opposite to that of ordinary ferromagnetic systems, namely, negative magnetocaloric effect. It was found that a large magnetic entropy change, ΔSmag, of 15 J/kg K is obtained under an applied field of 2 T. The adiabatic temperature change, ΔTad, reaches 5.4 K in a field change of 2 T. At higher magnetic fields, both ΔSmag and ΔTad retain a large value over wide temperature range, exhibiting characteristic temperature dependence of a trapezoidal shape. These features are attributed to a sharp first-order transition retained in high magnetic fields as well as small magnetocrystalline anisotropy.

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