Statistical mechanics of solid and liquid mixtures of ortho- and para-hydrogen: II
A. BabloyantzFaculty of Sciences , University of Brussels , Belgium ; The Naval Research Laboratory , University of WisconsinA. BellemansFaculty of Sciences , University of Brussels , Belgium ; Associé au Fonds National de la Recherche Scientifique (F.N.R.S.)
1960en
ABI
Annotatsiya
Various refinements are added to a previous theoretical calculation of the configurational free energy of condensed mixtures of o- and p-hydrogen, based on an oversimplified statistical model: (a) account is taken of the fact that the forces acting between o- and p-molecules are somewhat different and (b) the rigid lattice model previously used is replaced by an ensemble of Einstein oscillators. A better agreement with experiment is reached.
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