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Atomic arrangement in tellurite glasses studied by neutron diffraction

S. NeovInstitute of Nuclear Research and Nuclear Energetics, Bulgarian Academy of Sciences, SofiaI. GerassimovaInstitute of Nuclear Research and Nuclear Energetics, Bulgarian Academy of Sciences, SofiaK. KrezhovInstitute of Nuclear Research and Nuclear Energetics, Bulgarian Academy of Sciences, SofiaB. SydzhimovInstitute of Nuclear Research and Nuclear Energetics, Bulgarian Academy of Sciences, SofiaV. KozhukharovHigher Institute of Chemical Technology, Sofia
1978en
ABI

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A structural model on tellurite glasses, based on neutron diffraction data, is proposed. The coordination scheme of Te is determined and the binding system of the basic coordination polyhedra is establihsed. The role of the modifier (Fe2O3) in the glasses is discussed. The atomic density radial distribution function obtained, permits to conclude that the interatomic distances in the region 3.7 to 4.0 Å considerably increase at the vitreous state transition. [Russian Text Ignored].

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