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The Conformation of Odorants in Different States of Aggregation: A Joint Venture in Microwave Spectroscopy and X‐ray Diffraction

Halima MouhibInstitute of Physical Chemistry, RWTH Aachen University, 52056 Aachen (Germany),D. JelisavacInstitute of Physical Chemistry, RWTH Aachen University, 52056 Aachen (Germany),Wolfgang StahlInstitute of Physical Chemistry, RWTH Aachen University, 52056 Aachen (Germany),Ruimin WangInstitute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen (Germany),I. KalfInstitute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen (Germany),Ulli EnglertInstitute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen (Germany),

2011en

ABI

Annotatsiya

More than just the first X-ray structure: Microwave spectroscopy and theoretical calculations allow the authors to compare the structure of the volatile odorant allyl acetate (see picture) in the gas phase to its solid-state structure, which is based on diffraction experiments on high-quality binary crystals of cholic acid and the ester. An analogous comparison is successfully performed for isopropyl acetate. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

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Identifikatorlar

DOI: 10.1002/cphc.201000986

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