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Growth of β-Perylene Crystal

Tomoaki YagoNational Institute of Advanced Industrial Science and Technology (AIST)Yoshiaki TamakiNational Institute of Advanced Industrial Science and Technology (AIST)Akihiro FurubeNational Institute of Advanced Industrial Science and Technology (AIST)Ryuzi KatohNational Institute of Advanced Industrial Science and Technology (AIST)
2007en
ABI

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Abstract Although perylene crystals have been known to show both dimeric (α) and monomeric (β) phases, to date only the stable α-crystals have been obtained under conventional conditions. Here, we propose a procedure for the selective growth of β-phase perylene crystals, in which a saturated toluene solution at 350 K was cooled to 298 K with a high cooling rate (−30 K/min). The sizes of β-phase crystals obtained were in the order of 100 μm.

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