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Gas Phase Raman Intensities: A Review of “Pre-Laser” Data

William F. MurphyDivision of Pure Chemistry, National Research Council of Canada, Ottawa, CanadaWolfgang HölzerDivision of Pure Chemistry, National Research Council of Canada, Ottawa, CanadaH. J. BernsteinDivision of Pure Chemistry, National Research Council of Canada, Ottawa, Canada
1969en
ABI

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Raman radiant intensities and depolarization ratios measured for gases with mercury arc irradiation and photoelectric detection have been collected. The observed intensities have been reduced to values of the scattering activity, gj(45α j ′2 +7γ j ′2 ). The scattering activity and Raman scattering cross sections are explicitly related. Data for strong sharp bands are accurate to about ± 5% – 10%, while data for weak and broad bands are less accurate.

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