Ferrocenoyl-Substituted <i>Cinchona</i> Alkaloids: Synthesis, Structure, and Application in Asymmetric Catalytic Oxidation
Kilian MuñizKekulé-Department for Organic Chemistry and Biochemistry, Department for Inorganic Chemistry, University of Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, GermanyMartin NiegerKekulé-Department for Organic Chemistry and Biochemistry, Department for Inorganic Chemistry, University of Bonn, Gerhard-Domagk-Strasse 1, D-53121 Bonn, Germany
2003en
ABI
Annotatsiya
Ferrocenoyl-substituted Cinchona alkaloids were synthesized from ferrocenecarboxylic acid and the free Cinchona alkaloids and represent readily available organometallic auxiliaries. They were employed as a rare example of chiral ferrocenyl ligands in asymmetric oxidation chemistry.
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