Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation
Damir A. SafinDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5Yang XuDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5Ilia KorobkovDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5David L. BryceDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5Muralee MurugesuDepartment of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5
2013en
ABI
Annotatsiya
An unprecedented dinuclear heteroleptic CdII complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand, which can be seen as a triply fused terpyridine ligand. In the obtained complex, TPymT retains its structural integrity without undergoing oft-observed hydrolysis.
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