Hydrogen Clusters in Clathrate Hydrate
Wendy L. MaoDepartment of the Geophysical Sciences, University of Chicago, Chicago, IL 60637, USAHo‐kwang MaoGeophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USAAlexander F. GoncharovGeophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USAViktor V. StruzhkinGeophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USAQuanzhong GuoGeophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USAJingzhú HuGeophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USAJinfu ShuGeophysical LaboratoryRussell J. HemleyGeophysical Laboratory, Carnegie Institution of Washington, Washington, DC 20015, USAMaddury SomayazuluHigh Pressure Collaborative Access Team, Advanced Photon Source, Argonne National Laboratory, Argonne, IL 60439, USAYusheng ZhaoLos Alamos Neutron Science Center (LANSCE), Los Alamos National Laboratory, Los Alamos, NM 87545, USA
2002en
ABI
Annotatsiya
High-pressure Raman, infrared, x-ray, and neutron studies show that H2 and H2O mixtures crystallize into the sII clathrate structure with an approximate H2/H2O molar ratio of 1:2. The clathrate cages are multiply occupied, with a cluster of two H2 molecules in the small cage and four in the large cage. Substantial softening and splitting of hydrogen vibrons indicate increased intermolecular interactions. The quenched clathrate is stable up to 145 kelvin at ambient pressure. Retention of hydrogen at such high temperatures could help its condensation in planetary nebulae and may play a key role in the evolution of icy bodies.
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