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Elementary Excitations of a Linearly Conjugated Diatomic Polymer

Michael J. RiceXerox Webster Research Center, Webster, New York 14580E. J. MeléXerox Webster Research Center, Webster, New York 14580
1982en
ABI

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The low-lying particlelike excitations of a model linearly conjugated diatomic polymer, ${(A=B)}_{x}$, are found to be pairs of either spin-0 or spin-\textonehalf{} solitons with irrational charge values. The charge values and excitation energies are calculated as functions of the difference of the energy levels of the atomic $p$ orbitals of the two atomic constitutents of the unit cell. The phonon spectrum of the uniform polymer is also calculated.

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