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Aromatics, Reformulated Gasoline, and Atmospheric Organic Aerosol Formation

Jay R. OdumEnvironmental Engineering Science and Chemical Engineering, California Institute of Technology, Pasadena, California 91125T. P. W. JungkampEnvironmental Engineering Science and Chemical Engineering, California Institute of Technology, Pasadena, California 91125Robert J. GriffinEnvironmental Engineering Science and Chemical Engineering, California Institute of Technology, Pasadena, California 91125Hali J. L. ForstnerEnvironmental Engineering Science and Chemical Engineering, California Institute of Technology, Pasadena, California 91125Richard C. FlaganEnvironmental Engineering Science and Chemical Engineering, California Institute of Technology, Pasadena, California 91125John H. SeinfeldEnvironmental Engineering Science and Chemical Engineering, California Institute of Technology, Pasadena, California 91125
1997en
ABI

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Secondary organic aerosol (SOA) yield curves have been obtained for 17 individual aromatic species from an extensive series of sunlight-irradiated smog chamber experiments. These yield curves, interpreted within the framework of a gas/aerosol absorption model, are used to quantitatively account for the SOA that is formed in a series of smog chamber experiments performed with the whole vapor of 12 different reformulated gasolines. The total amount of secondary organic aerosol produced from the atmospheric oxidation of whole gasoline vapor can be represented as the sum of the contributions of the individual aromatic molecular constituents of the fuel.

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