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Conversion of Methanol to Hydrocarbons: How Zeolite Cavity and Pore Size Controls Product Selectivity

Unni OlsbyeDepartment of Chemistry, inGAP Centre of Research-based Innovation, University of Oslo, P.O. Box 1033 Blindern, 0315 Oslo, Norway. [email protected]Stian SvelleDepartment of Chemistry inGAP Centre of Research-based Innovation, University of Oslo, P.O. Box 1033 Blindern, 0315 Oslo (Norway) http://www.mn.uio.no/ingapMorten BjørgenDepartment of Chemistry, Norwegian University of Science and Technology, 7491 Trondheim (Norway)Pablo BeatoHaldor Topsøe, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Ton V. W. JanssensHaldor Topsøe, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Finn JoensenHaldor Topsøe, Nymøllevej 55, 2800 Kgs. Lyngby (Denmark)Bordiga, SilviaDepartment of Chemistry, NIS Centre of Excellence, University of Torino, Via P. Giuria 7, 10125 Turin (Italy)Karl Petter LillerudDepartment of Chemistry inGAP Centre of Research-based Innovation, University of Oslo, P.O. Box 1033 Blindern, 0315 Oslo (Norway) http://www.mn.uio.no/ingap

2012en

ABI

Annotatsiya

Liquid hydrocarbon fuels play an essential part in the global energy chain, owing to their high energy density and easy transportability. Olefins play a similar role in the production of consumer goods. In a post-oil society, fuel and olefin production will rely on alternative carbon sources, such as biomass, coal, natural gas, and CO(2). The methanol-to-hydrocarbons (MTH) process is a key step in such routes, and can be tuned into production of gasoline-rich (methanol to gasoline; MTG) or olefin-rich (methanol to olefins; MTO) product mixtures by proper choice of catalyst and reaction conditions. This Review presents several commercial MTH projects that have recently been realized, and also fundamental research into the synthesis of microporous materials for the targeted variation of selectivity and lifetime of the catalysts.

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Identifikatorlar

DOI: 10.1002/anie.201103657

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