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Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering

Meiling XiaoState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaYongting ChenHubei Electrochemical Power Sources Key Laboratory, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, ChinaJianbing ZhuState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaHao ZhangShanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, ChinaXiao ZhaoInnovation Research Center for Fuel Cells University of Electro-Communications, Chofugaoka, Chofu, Tokyo 182-8585, JapanLiqin GaoState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaXian WangState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaJin ZhaoState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaJunjie GeState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaZheng JiangShanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, ChinaShengli ChenHubei Electrochemical Power Sources Key Laboratory, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, ChinaChangpeng LiuState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, ChinaWei XingState Key Laboratory of Electroanalytical Chemistry, Jilin Province Key Laboratory of Low Carbon Chemical Power, Changchun Institute of Applied Chemistry Chinese Academy of Sciences, Changchun 130022, China
2019en
ABI

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site. Our finding not only opens up a novel strategy to tailor the electronic structure of an atomic site toward boosted activity but also provides new insights into the fundamental understanding of diatomic sites for ORR electrocatalysis.

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