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Adsorption Energy in Oxygen Electrocatalysis

Junming ZhangSchool of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, SingaporeHong Bin YangSchool of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, SingaporeDaojin ZhouDepartment of Electrical and Computer Engineering, University of Toronto, 35 St. George Street, Toronto, Ontario M5S 1A4, CanadaBin LiuSchool of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, Singapore

2022en

ABI

Annotatsiya

Adsorption energy (AE) of reactive intermediate is currently the most important descriptor for electrochemical reactions (e.g., water electrolysis, hydrogen fuel cell, electrochemical nitrogen fixation, electrochemical carbon dioxide reduction, etc.), which can bridge the gap between catalyst's structure and activity. Tracing the history and evolution of AE can help to understand electrocatalysis and design optimal electrocatalysts. Focusing on oxygen electrocatalysis, this review aims to provide a comprehensive introduction on how AE is selected as the activity descriptor, the intrinsic and empirical relationships related to AE, how AE links the structure and electrocatalytic performance, the approaches to obtain AE, the strategies to improve catalytic activity by modulating AE, the extrinsic influences on AE from the environment, and the methods in circumventing linear scaling relations of AE. An outlook is provided at the end with emphasis on possible future investigation related to the obstacles existing between adsorption energy and electrocatalytic performance.

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Identifikatorlar

DOI: 10.1021/acs.chemrev.1c01003

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