Article

Desolvation Mechanism of Crystalline Host-Guest Compounds Considering Pseudopolymorphism: Study of the 1,1′-Binaphthyl-2,2′-Dicarboxylic Acid Clathrates with DMF

К. М. БекетовInstitut für Organische Chemie der Technischen Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen (Germany)Edwin WeberInstitut für Organische Chemie der Technischen Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen (Germany)Б. Т. ИбрагимовInstitute of Bioorganic Chemistry, Uzbekistan Academy of Sciences, H. Abdullaev Str. 83, Tashkent, 700143 (Uzbekistan)Jürgen SeidelInstitut für Physikalische Chemie der Technischen Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen (Germany)K. KöhnkeInstitut für Physikalische Chemie der Technischen Universität Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg/Sachsen (Germany)

Advanced Materialsjournal2000en

ABI

Abstract

Inclusion compounds have significant potential as chemical receptors for sensors; however, it is necessary to understand the encapsulation and release processes for such applications. These authors have utilized the powerful combination of simultaneous thermogravimetry and differential scanning calorimetry and X-ray diffraction to study the decomposition mechanism of the clathrates between 1,1′-binaphthyl-2,2′-dicarboxylic acid (BNDA) and dimethyl formamide (DMF). Decomposition was found to proceed via three intermediate phases whose structures were determined by single crystal X-ray crystallography.

Topics

Analytical Chemistry and Chromatography Thermal and Kinetic Analysis Synthesis and properties of polymers

Identifiers

DOI: 10.1002/(sici)1521-4095(200005)12:9<664::aid-adma664>3.0.co;2-w

Citations and references

Cited by 20 references

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