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Cooperative interactions in the lattice of LaF3-Type superionic crystals

V. F. KrivorotovHeat Physics Department, Uzbek Academy of Sciences, ul. Katartal 28, Chilanzar, Tashkent, 100135, Uzbekistan
Technical Physicsjournal2013en
ABI

Abstract

The mechanism and energy parameters of cooperative interactions between point defects, vacancies, and interstitial ions, in the lattice of LaF3-type superionic trifluorides are studied. The mean energy of interaction between two pairs of the defects is determined (λ = 0.032 eV) in the dipole approximation. It is shown that cooperative interactions in the “quasi-liquid” lattice of LaF3 decrease the defect formation energy down to values on the order of ≈kT.

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