Article

Functionalization-Induced Phase Separation Produces MWNTs/UHMWPE Microspheres with Size-Dependent Nanotube Localization

Moulay Rachid BabaaArts et Metiers Campus of Rabat (EAMR), Parc Technopolis, 11100 Sala Al Jadida, Morocco

ChemRxivrepository2025

ABI

Abstract

Functionalization-induced solubility collapse produces MWNTs/UHMWPE microspheres with size-dependent architectures. A bifunctional linker and a coupling agent trigger rapid phase segregation and MWNTs interfacial migration, yielding CNT-rich droplets. Larger droplets develop CNT-enriched shells, while smaller ones retain CNTs in their cores. SEM, TEM, and XRD confirm unique core-shell-corona structures.

Topics

Pickering emulsions and particle stabilization Surface Modification and Superhydrophobicity Block Copolymer Self-Assembly

Identifiers

DOI: 10.26434/chemrxiv-2025-tsgml

Citations and references

Cited by 00 references

Metrics — AkademScholar · Coming soon