Diaquadichloridobis[quinazolin-4(1<i>H</i>)-one-κ<i>N</i><sup>3</sup>]copper(II)
K. K. TurgunovS.Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan, Mirzo Ulugbek Str. 77, Tashkent 100170, UzbekistanShirin ShomurotovaTashkent State Pedagogical University Named After Nizami, Yusuf Khos Khojib Str. 103, Tashkent 100100, UzbekistanН. С. МухамедовS.Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan, Mirzo Ulugbek Str. 77, Tashkent 100170, UzbekistanB. TashkhodjaevS.Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan, Mirzo Ulugbek Str. 77, Tashkent 100170, Uzbekistan
ABI
Аннотация
In the title complex, [CuCl(2)(C(8)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) ion is located on an inversion center and is octahedrally coordinated by two N atoms of the 1H-quinazolin-4-one ligand, two chloride ligands and two aqua ligands. The axial Cu-O distances are significantly longer [2.512 (2) Å], than the Cu-N [2.022 (2) Å] and Cu-Cl [2.3232 (4) Å] distances as a result of Jahn-Teller distortion. Aqua ligands are involved in intra- and inter-molecular hydrogen bonding, and N-H⋯O inter-molecular hydrogen bonds are formed between the organic ligands. In addition, weak π-π inter-actions are observed between the benzene rings of the ligand [centroid-centroid distance = 3.678 (1) Å].
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