Sodium Ferrate Synthesized in a Solar Furnace: a Cathode Material for a Sodium-Ion Battery
Аннотация
It has been shown that a material based on sodium ferrate NaFeO2 can be obtained by synthesis from a melt in a solar furnace. The crystal structure is tetragonal with the lattice parameters of a = 5.638 Å, b = 5.672 Å, and c = 7.279 Å. The average particle size of the material is 1.2 μm. It has been found that the NaFeO2 material sample provides the oxidation–reduction activity of Na+/Na and the oxidation–reduction activity of Fe2+/Fe3+. Therefore, NaFeO2 can be a potential material for the cathode of a sodium-ion battery with a specific capacity of 110 mAh/g. It has been found that sodium ferrate NaFeO2 exhibits sufficiently good resistance to water. That is, sodium ferrate does not decompose in water at 80–100°C.
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