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Reductive acylamination of pyridine N-oxide with ethylenediamine and phenylenediamines

Yu. V. KurbatovAlisher Navoi Samarkand State University, Universitetskii bul’var 15, Samarkand, 703004, UzbekistanM. A. SolekhovaAlisher Navoi Samarkand State University, Universitetskii bul’var 15, Samarkand, 703004, Uzbekistan

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Reactions of pyridine N-oxide with ethylenediamine and o- and p-phenylenediamines in the presence of p-toluenesulfonyl chloride in alkaline medium lead to the formation of the corresponding N,N′-bis-(p-tolylsulfonyl)-N,N′-bis(pyridin-2-yl)diamines as a result of reductive acylamination.

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