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Semimetal–semiconductor transition with a change in the thickness of a bismuth–antimony alloy thin film

E. I. BukhshtabPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kovYu. F. KomnikPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kovYu. V. NikitinPhysicotechnical Institute of Low Temperatures, Academy of Sciences of the Ukrainian SSR, Khar’kov
ABI

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The changes in the electrical resistance and the magnetoresistance coefficient have been studied for Bi films and Bi1−x Sbx alloys (x = 0.168) at 4.2 and 300 °K with an increase of thickness L from 4 to 10 μ. It has been established previously that in the region of composition with x > 0.065 which corresponds to the semiconductor spectrum in bulk crystals, in films less than 2μ thick there is a semimetallic state due to the change in the structure of the spectrum under the influence of the film potential. A comparison of the behavior of the resistance and magnetoresistance of bismuth and alloy films in the region of large thicknesses allows one to establish that in Bi0.83Sb0.17 alloy films with L > 7 μ there is a decrease in the carrier concentration which indicates a semimetal-semiconductor transition with increasing film thickness.

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