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Phase transformations in titanium oxycarbide TiC0.545O0.08

M. Yu. TashmetovInstitute of Nuclear Physics, Academy of Sciences of Uzbekistan, Tashkent, 702132, UzbekistanВ. Т. ЭмInstitute of Nuclear Physics, Academy of Sciences of Uzbekistan, Tashkent, 702132, UzbekistanБ. Н. СавенкоJoint Institute for Nuclear Research, Dubna, Moscow oblast, 141980, RussiaG. BatdemberelInstitute of Physics and Technology, Mongolian Academy of Sciences, Ulan Bator, Mongolia
Crystallography Reportsjournal2003en
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Phase transformations in titanium oxycarbide TiC0.545O0.08 have been studied by the methods of neutron diffraction and X-ray structure analysis. It was established that the ordered cubic structure δ′ (sp. gr. Fd3m) of the oxycarbide sample is the low-temperature ordered phase existing up to 990 K. The order-disorder phase transition (990 K) results in the formation of an ordered trigonal structure (sp. gr. or R3m or P3121). The α-Ti-phase is separated at the temperature 1020 K. The order-disorder phase transition was found at T = 1040 K.

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