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<i>S</i>,<i>S</i>′-(Pyridazine-3,6-diyl)dithiouronium dichloride methanol monosolvate

Jörg HübscherInstitut für Organische Chemie, TU Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg/Sachsen, GermanyL. Yu. IzotovaInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek Str. 83, 100125 Tashkent, UzbekistanSamat A. TalipovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek Str. 83, 100125 Tashkent, UzbekistanFelix KatzschInstitut für Organische Chemie, TU Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg/Sachsen, GermanyEdwin WeberInstitut für Organische Chemie, TU Bergakademie Freiberg, Leipziger Strasse 29, D-09596 Freiberg/Sachsen, Germany

Acta Crystallographica Section E Structure Reports Onlinejournal2011en

ABI

Annotatsiya

In the title compound, C(6)H(10)N(6)S(2) (2+)·2Cl(-)·CH(3)OH, the pyrid-azine ring is almost planar, the greatest deviation from the mean plane being 0.025 (2) Å for one of the ring N atoms. The two thiouronium substituents are tilted out of this plane by 60.87 (6) and 57.94 (7)°. The thiouronium cations and the chloride anions are linked by strong N-H⋯Cl hydrogen bonds. The methanol solvent mol-ecule inter-acts with both the chloride ion (through an O-H⋯Cl hydrogen bond) and the cation (through an N-H⋯O hydrogen bond), resulting in a three-dimensional supra-molecular arrangement.

Mavzular

Crystal structures of chemical compounds Synthesis and Characterization of Heterocyclic Compounds Organometallic Compounds Synthesis and Characterization

Identifikatorlar

DOI: 10.1107/s1600536811018514

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