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A Microporous Metal–Organic Framework for Highly Selective Separation of Acetylene, Ethylene, and Ethane from Methane at Room Temperature

Yabing HeDepartment of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USAZhangjing ZhangDepartment of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698 (USA),Shengchang XiangDepartment of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698 (USA),Frank R. FronczekDepartment of Chemistry, Louisiana State University, Baton Rouge, LA 70803-1804 (USA)Rajamani KrishnaBanglin Chen, Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698 (USA),Banglin ChenBanglin Chen, Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698 (USA),

2011en

ABI

Annotatsiya

A novel three-dimensional microporous metal-organic framework Zn(4)L(DMA)(4) (UTSA-33, H(8) L=1,2,4,5-tetra(5-isophthalic acid)benzene, DMA=N,N'-dimethylacetamide) with small pores of about 4.8 to 6.5 Å was synthesized and structurally characterized as a non-interpenetrated (4,8)-connected network with the flu topology (Schläfli symbol: (4(12)6(12)8(4))(4(6))(2)). The activated UTSA-33a exhibits highly selective separation of acetylene, ethylene, and ethane from methane with the adsorption selectivities of 12 to 20 at 296 K, which has been established exclusively by the sorption isotherms and simulated breakthrough experiments, thus methane can be readily separated from their binary and even ternary mixtures at room temperature.

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Identifikatorlar

DOI: 10.1002/chem.201102734

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