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Ish: A Microporous Metal–Organic Framework for Highly Selective Separation of Acetylene, Ethylene, and Ethane from Methane at Room Temperature

1. An aminopyrimidine-functionalized cage-based metal–organic framework exhibiting highly selective adsorption of C₂H₂ and CO₂ over CH₄

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2. An anionic metal–organic framework based on angular tetracarboxylic acid and a mononuclear copper ion for selective gas adsorption

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