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Electronic States of the Conduction Band of Ultrathin Furan-Phenylene Co-Oligomer Films on the Surfaces of Oxidized Silicon and Layer-by-Layer Grown Zinc Oxide

А. S. KomolovSt. Petersburg State University, St. Petersburg, RussiaИ. А. ПронинPenza State University, Penza, RussiaЭ. Ф. ЛазневаSt. Petersburg State University, St. Petersburg, RussiaВ. С. СоболевSt. Petersburg State University, St. Petersburg, RussiaЕ. А. ДубовSt. Petersburg State University, St. Petersburg, RussiaA. A. KomolovaSt. Petersburg State University, St. Petersburg, RussiaEvgeniy V. ZhizhinSt. Petersburg State University, St. Petersburg, RussiaД. А. ПудиковSt. Petersburg State University, St. Petersburg, RussiaS. A. PshenichnyukInstitute of Molecule and Crystal Physics, Ufa Federal Research Centre, Russian Academy of Sciences, Ufa, RussiaCh. S. BeckerVorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, RussiaMaxim S. KazantsevVorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, RussiaFeruza AkbarovaPhysical–Technical Institute, Uzbekistan Academy of Sciences, Tashkent, UzbekistanUtkirjon SharopovBukhara State University, Bukhara, Uzbekistan
Crystallography Reportsjournal2024en
ABI

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The results of studying the electronic states of the conduction band of ultrathin films of furan-phenylene co-oligomer 1,4-bis(5-phenylfuran-2-yl)benzene and the results of analyzing the interfacial potential barrier upon the formation of these films on the surfaces of (SiO2)n-Si and layer-by-layer deposited ZnO are presented. The formation of a (8–10)-nm-thick co-oligomer film was investigated by total current spectroscopy; the energy range from 5 to 20 eV above EF was analyzed. Furan-phenylene co-oligomer films on the (SiO2)n-Si surface have a domain structure with a characteristic domain size of ~1 × 1 µm and surface roughness within a domain of no more than 1 nm. The films on the ZnO surface have a granular structure with a grain height of 40–50 nm.

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