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Synthesis and Crystal Structure of Bis(2,6-diaminopyridinium) Tetrachlorozincate(II)

Yusufjon NazarovTermez State University, Termez, UzbekistanKh. Kh. TuraevTermez State University, Termez, UzbekistanJamshid AshurovSadykov Institute of Bioorganic Chemistry, Academy of Sciences of the Republic of Uzbekistan, Termez, UzbekistanSh. A. KasimovTermez State University, Termez, UzbekistanZh. R. SuyunovTermez State University, Termez, UzbekistanN. A. ErmuratovaTermez Institute of Engineering and Technology, Termez, UzbekistanK. N. KornilovRussian Biotechnological University (BIOTECH), 121205, Moscow, Russia

Crystallography Reportsjournal2025en

ABI

Annotatsiya

The new bis(2,6-diaminopyridinium) tetrachlorozincate complex of the composition (С5Н8N $$_{3}^{ + }$$ )2[ZnCl4]2– was synthesized by the reaction of 2,6-diaminopyridine with a Zn(II) ion in an ethanolic solution of hydrochloric acid. The composition and the molecular and crystal structure of the synthesized complex were determined by X-ray diffraction analysis. The composition of the metal complex was confirmed by elemental analysis. The chemical bonds were investigated by IR spectroscopy. Intermolecular interactions in the crystal were studied by the Hirshfeld surface analysis. The stability of the complex was determined by thermal analysis and it is, apparently, attributed to intramolecular hydrogen bonds.

Mavzular

Crystal structures of chemical compounds Metal complexes synthesis and properties Organometallic Compounds Synthesis and Characterization

Identifikatorlar

DOI: 10.1134/s106377452460220x

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