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Novel Copper Oxide Phyto-Nanocatalyst Utilized for the Synthesis of Sustainable Biodiesel from Citrullus colocynthis Seed Oil

Aqsa AzizPlant Systematics and Biodiversity Lab Department of Plant Sciences, Quaid-i-Azam University, Islamabad 45320, PakistanMushtaq AhmadPakistan Academy of Sciences, Islamabad 44000, PakistanMuhammad Zafar-ul-HyePlant Systematics and Biodiversity Lab Department of Plant Sciences, Quaid-i-Azam University, Islamabad 45320, PakistanAbdel‐Rhman Z. GaafarDepartment of Botany and Microbiology, College of Science, King Saud University, Riyadh P.O. Box 11451, Saudi ArabiaMohamed S. HodhodFaculty of Biotechnology, October University for Modern Sciences & Arts, 6th October City 12566, EgyptShazia SultanaPlant Systematics and Biodiversity Lab Department of Plant Sciences, Quaid-i-Azam University, Islamabad 45320, PakistanMohammad AtharCalifornia Department of Food and Agriculture, Pest Detection & Emergency Projects, 1220 ‘N’ Street, 2nd Floor, Sacramento, CA 95814, USAFethi Ahmet ÖzdemirDepartment of Molecular Biology and Genetics, Faculty of Science and Arts, Bingol University, Bingol 12000, TurkeyTrobjon MakhkamovDepartment of Forestry and Landscape Design, Tashkent State Agrarian University, 2 A., Universitet Str., Kibray District, Tashkent 100700, UzbekistanAkramjon YuldashevDepartment of Ecology and Botany, Andijan State University, 129, Universitet Str., Andijan 170100, UzbekistanOybek MamarakhimovDepartment of Ecology Monitoring, National University of Uzbekistan, 4 University Street, Tashkent 100174, UzbekistanMaxsuda NizomovaDepartment of Medicinal Plants, Tashkent State Agrarian University, 2 A., Universitet Str., Kibray District, Tashkent 100700, UzbekistanSalman MajeedDepartment of Botany, University of Mianwali, Mianwali 42200, PakistanBisha ChaudhayPlant Systematics and Biodiversity Lab Department of Plant Sciences, Quaid-i-Azam University, Islamabad 45320, Pakistan
Processesjournal2023en
ABI

Annotatsiya

The green chemistry method for nanocatalyst synthesis along with environmentally feasible non-edible sources are promising alternatives to fossil fuels. The current study focuses on the synthesis of copper oxide phyto-nanocatalyst and the identification of a new renewable feedstock, Citrullus colocynthis, to reduce environmental pollution. The highest biodiesel yield (95%) was obtained under optimum conditions of a 1:8 oil-to-methanol ratio and reaction temperature of 85 °C for 120 min with a 0.365 wt% catalyst concentration. The phyto-nanocatalyst was synthesized using seed oil cake after extracting oil with the salt of copper (copper oxide). The catalyst was then subjected to various analyses, namely, EDX, FT-IR, SEM, and XRD. The catalyst was proved to be efficient and effective after being reused five times and still there was a very small difference in biodiesel yield. All the analyses also show sustainable and stable results. Thus, copper oxide phyto-nanocatalyst with non-edible Citrullus colocynthis proved to be highly effective, sustainable, and a better alternative source to the future biodiesel industry.

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